We really need to see a schematic of the circuit you're experiencing problems with.
The schematic you posted "would" send DC voltage to the guitar because bias voltage is applied to the base (input) of transistor TR1 near the input, through resistor R15. Voltage is prevented from leaking back into the guitar by capacitor C8.
However, that bias technique is particular to the type of transistor used in that circuit. It has nothing to do with the tubes in that circuit, and it's not a good analogy of any other tube circuit I know of.
Both tubes used in that circuit are connected in a way that should not bleed voltage back onto the guitar... regardless of the circuit/capacitors between the tube and guitar. Yes, each tube is driven through 100n capacitors but this is needed to "protect" the tube from DC voltage before it in the circuit, not the other way around. The grid (input) of each tube section should be at ground (0 volts).
Again, a faulty tube could cause all sorts of trouble, even though there is no explanation for this is "normal" operation. Have you tried another tube to see if it fixed the problem?
Also, are you experiencing trouble with that exact circuit? If so, this is an issue with the SS circuit before the tube, not the tube itself. It sounds like you understand that but you haven't provided us enough info to tell you what or where the problem is.