You can probably skip the grid leak, you've got a ground reference through the tonestack and adding more would increase the load on the tonestack (reducing volume and/or changing tone behavior). Now, I guess removing the MV from ground with no added grid leak decreases the load, but you're going for max volume so that might be a step in the right direction.
If you wanted to get fancy you could use a relay (to avoid picking up noise or stray capacitance or whatever outside the amp). To get really fancy you could use a dual-pole relay (or dual pole switch in the footswitch) to switch the signal from the wiper of the pot to the top of the pot, therefore keeping it in place and not messing with the grid leak arrangement. With this said, you're temporarily removing the grid from any connection/reference so I expect this is more prone to popping and other noise than less-direct changes like grounding.
Edit: On second thought, it's probably not the "best idea" to ever remove the grid/bias reference from the power tube, even temporarily.
But you could use a dual-pole switch and/or relay to remove the ground of the MV *and connect a parallel 1M grid leak in its place*. This way, the grid leak loads the circuit back to regular configuration in the lead setting, but is unconnected in the normal setting.
The best part of this, compared to my previous suggestion, is if these connections fail and neither is connected at all, you still get a ground reference through the tonestack for safe/consistent bias.