You must understand the operation of the downstream circuit if you want to check for cap leakage in circuit. I can think of three common circuits that will always have voltage on the downstream side of a coupling cap,,, cathode follower grid, LTP PI grids, fixed bias output tube grids. There's only one way to accurately check for cap leakage in these three examples. You must disconnect the downstream lead of such a coupling cap. Another not so common example is a grid leak biased tube. They operate with the grid at a negative voltage and the cathode is usually connected to ground. In fact, any tube that has it's cathode connected to ground will have a negative voltage on the grid.
And then there's the crazy way the 5E3 volume control is wired! If the volume control is set to zero and you're trying to check for cap leakage, the downstream side of leaky coupling cap will be at ground and falsely show no leakage. But turn the vol pot up and there is the leaky voltage.
These are just common examples of circuits that you must disconnect the downstream side of the cap to properly check for leakage. I'm sure there are other examples. If you didn't know some or all of this, then I advise you to ***ALWAYS*** disconnect the downstream lead of a suspected leaky cap. Then you will ***KNOW*** for sure.
what about testing for DCV on the pots.
Good point. But here again, you must know how to analyze a circuit. Look at the INTENSITY pot in a Princeton Reverb. The pot has a negative voltage on all three pot lugs. You would have to disconnect the downstream side of that .1µF coupling cap to test for leakage.
Sometimes it's perfectly normal for voltage to be present on both sides of a coupling cap.