Yup, PRR nailed it, (as usual). if you want to use a type of MV, you need a push pull preamp type that gets your drive in the preamp stages, then you use a PPIMV (Post Phase Inverter Master Volume) that is a dual pot that you send both outputs of the PI into and in parallel you lower the volume by increasing the resistance forward while decreasing the resistance to ground. I think most Single Ended amps tend to sound like they do because you can drive the power stage a lot harder and get a different tone to the overdrive. I'm guessing you could up the drive on a SE amp by adding another gain stage and then just put a second Master Volume before the output (there's no PI in a SE amp).
(or so my yeoman's level learning suggests)
As far as adding a speaker jack, as stated, it exists already in the champ, but if you don't have a schematic with one, you can always add it, but you need to be careful to do one of two things:
1. ensure the jack, when connected, shuts off output to the other speaker so you don't mess up the total speaker impedance, or
2. convert the internal speaker to use the same output jack and that way you just unplug the built in one, and plug in the external one.
Fenders tend to always go the route of using a jack on the chassis for the speaker. I've seen it on several at this point, only the really old ones (like the bassman clone) have something a bit different (the bassman had 4 rca outputs and you needed to connect 4x8 ohms or some total of 2 ohms.)
Just make sure to match impedance correctly for the OT.
~Phil