Colas,
Always good to see you on the forum! My experience using four gain stages for overdrive (mostly Dumblish inspired stuff) is that there are numerous factors in getting a pleasant overdrive & distortion beyond just the master volume allowing the overdrive/distortion.
Looking at all the Dumble schematics, some of the Mesa Boogie schematics, some of the Cornford schematics …..
there is something of a pattern that shows up.
- smaller value coupling caps with 4 gain stages then 2 or 3 gain stages
- smaller value cathode caps with more gain stages
- smoothing caps
In addition in the D-inspired amps like the D'Mars, Tweed Overdrive Special, Tweed BluezMeister and Carolina Overdrive Special, things like the type of caps used (Orange Drop polyester) and plate resistors (such as Vishay-Dale RN65 or larger wattage metal film) and cap orientation all seem to play a factor in smoothness.
Other thoughts to allow overdrive and distortion are the different type of master volumes. Pre-LTPI, PPIMV, the type shown by Papa Jim, using a VVR with cathode biased amps (just on the power tubes and LTPI but not preamp tubes), and DaGeezer's great cathode-attenuation method are all considerations given the amp design and other factors.
So, in my opinion, I don't find the master volume to be the issue. I find the right values and types of caps, types of resistors, cap orientation, plate voltages and other factors to be the context that the master volumes work well or poorly.
Just some thoughts to ponder.
I've heard your guitar playing (including that incredible Johnny Winter cover you mailed me years ago & the Alvin Lee impersonation). I wish I had 1/10 of your talent because IF I did then I'd be twice as good of a player as I currently am. Needless to say, I am a big fan of your playing.
I'd love for you to have an amp that gives you the overdrive/distortion tone that is a good match for the phenomenal talent you have been given and honed.
I think IF you don't factor in other variables and you are just wanting a master volume to dial in the tone you're looking for that you may be chasing your tail. Again, just some thoughts to ponder.
With respect, Jeff