What you planned to do is exactly how I normally mount the OT. My primary reason is simply aping what I've seen in most Fender and Marshall amps. I stick with what works.
Some folks have advocated placing the PT and OT on opposite ends of the chassis. The primary (maybe only) benefit of this choice is that the weight of the chassis is more balanced (it doesn't lean excessively to one side when picked up), and the transformers' weight is moved closer to the vertical sides of the chassis where the whole structure is stiffer.
But I think people overlook the steps taken to make this work. People might cite Hiwatt as an example of transformers at opposite ends of the chassis, but few of these folks have ever seen a Hiwatt in person (I used to own a 70's DR504). The chassis is
very spacious. I don't know the exact measurements, but look at a
picture of a DR504 and note how much depth the chassis has. A
view from the rear shows that the output tubes are larger than typical EL34's, so they are likely American-made 6CA7's, with large bottles. The OT is on the right in the rear-view, near the white jacks. If you pay close attention, the OT is indeed on the "input" side of the amp, with the PT on the same side as the power and standby switches.
The problem with having an OT on the input side of the amp is that the primary wires connecting to the tube plates have large signals present. Big voltages, big (relative to the rest of the amp circuit) currents. Any wire carrying a.c. has a field around the wire; the bigger the a.c. (in voltage or current terms), the bigger and stronger the field. Any nearby wiring can potentially act as an antenna to pick up this field, especially high impedance circuits (such as those found at tube grids). The objection to having the OT anywhere near the input jacks (or other high impedance wiring) is the possibility of oscillation due to coupling the output of a circuit back to the input.
So how does Hiwatt get away with doing this? Look closely at the
inside of the DR504 chassis. The input jacks are at the top left of the image, and the OT wiring and speaker jacks are at the bottom left. There is quite a lot of distance between the wiring for the OT and the input wiring, and each are dressed in opposite direction to minimize any coupling. Further, that gray input jack wiring is shielded wire, and the shield is only cut right near the grid pin of the tube socket (and right at the input jack lug).
I'll argue that's much more distance than commonly seen in any amp where folks attempt to place the transformers on opposite ends of the chassis. If we try to estimate the distance based on the landmarks we have (tube socket holes, cap can holes), I would not be surprised if it's 8-10 inches or more. That's likely more distance than found in a tweed chassis.
So transformer placement depends on the chassis you're working with, and the layout you choose to use. But you always want to keep high-level signal wiring away from low-level high-impedance wiring. Chip's comments regarding transformer fields are still applicable, however coupling due to the transformer fields decreases with distance, and there is so much distance between transformers in the Hiwatt example that hum due to this cause is non-existent.