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Every cap manufacturer would have different ideasThey do. And different in different times.
Old-old ratings were "Working Volts" and "Surge".
Fire-up the amp. When rectifier warms, first cap shoots to say 420V. when 6V6 warms, votage drops to say 360V. You need 425V Surge, 375V Working.
Modern cap specs get very exacting. There is a "life" for a certain Voltage and Temperature, with derating for some other stresses. Often the Life is only 1,000 hours. However this is at MAXimum rated temperature. Info is given for estimating life at other temperatures.
Life doubles for every 10 degrees C cooler than rated temperature. If you can stay below 50 deg C, life is long; above 65 deg C you should consider better location, hi-Temp caps, or occasional replacement.
But what about voltage?? Well, voltage is good but excess voltage is excess leakage, which is heat, see above.
And that's why "Surge" rating has vanished (aside from most stuff not needing warm-up today). The turn-on overvoltage hits a cold cap. Temp won't rise much in a few seconds, even a minute or so.
However the life computed from temperature may be extended if you don't need the full voltage.
http://www.niccomp.com/Products/General/Alumlyticlifeexpect.pdf -- Fig 1
Time to failure may double if you only need 0.7 of the rated voltage. Triple at 0.4 rated voltage.
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My unloaded voltage should be around 458v w/ ss rectification on a 325v PT450V cap is fine for breadboard. The B+ will probably sag in all normal use. We all have amps with 430V-444V on 450V caps giving everyday service.
500V cap may be a better bet. In part because the few 500V cap makers know what you are doing (tube amps) and value your business. You aren't the far fringe of a billion-cap market to them.
2*350V is also fine, but violates the K.I.S.S. rule.
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to raise B+Why?