I'm pretty sure it's 60 cycle hum but how do you tell the difference?
I'm fortunate, in that my DMM (an older Fluke 87III) has a frequency counter. If your meter has such a function, use it (though you will likely have to dig through the manual to find how to use it and its limitations.
If no counter is available, try playing a B-flat on your low E string. 120Hz is an out-of-tune B-flat, while 60Hz is the same note an octave lower (lower than your low E note). Buzzy hum (usually from no heater ground reference) can make it hard to discern the pitch because of all the harmonics of the hum, which is why it sounds buzzy.
What does the extra 20uf and the 250 ohm R do to cut hum...?
Note the output transformer sources B+ from the first filter cap attached to the rectifier output. That is the noisiest B+ in the amp; subsequent series-resistors and filter caps to ground successively remove ripple from the B+, with the preamp getting the cleanest d.c.
A lot of folks here have built Champs over the years, many using heavier OTs and speakers as big as 12". The bigger OT and speaker have better bass response than the Champ's original 8" speaker. As a result, those builders hear hum in their amps that was always there, but which the puny OT/speaker shaved off.
Push-pull amps have no problem attaching the OT to the noisiest filter in the power supply, because the power is fed to the center-tapped primary: hum voltages travel in opposite directions through the primary and cancel. But single-ended amps don't get the benefit of this, and need extra filtering to sound noise-free.
The universal solution has been to add another filter cap to ground before the one feeding the OT, with a resistor or a choke between the new cap and the existing B+ rail. This trims ripple from the power supply before it is fed to the OT. An added C-R or C-L filter is a much better filter than just increasing filter cap values.
A lot of folks never realize that hum in their Champ is mostly a power supply issue, and that the heaters are rarely a problem. But they jump to solutions they've read about elsewhere, never realizing the original Champ was hamstrung by the weak bass response of a small OT and speaker, which reduced any hum to "acceptable level".