Sure, but:
Working at 240V 60Hz, the transformer wants to distort.
When driven by a MegaWatt electric company, the distortion is mild and we really don't care.
When driven by a skinny vacuum tube, the distortion can be severe.
Inversely proportional to frequency. At 82Hz you can hit it 1.36 times higher voltage for the same distortion.
Proportional to voltage. For pretty-clean output at power frequency you want the plate swing to be much less than design voltage. Even 1/3rd of design. So "120VAC" is good for about 40VAC at 60Hz. That's 56V peak. Adding tube losses we might aim at 80V-120V of B+. This is quite low by our standards.
Look another way. A "6VAC" winding will distort bad at 6V (60Hz) or 8V (82Hz). For real-clean we drop to 1.5V-2V. That much voltage in 4 ohms is 0.5W-1W of clean power. 9W-16W very-bent power. NOT a large power.
In special cases (harmonica, ocarina, small female singers) you might aim at 250Hz. Then you can apply much higher voltage and stay clean.
Aside from all that: power transformers are fairly sure to pass 50/60Hz to about 400hz (rectifier harmonics). Anything more is incidental, and not really a bonus for power use. Simple all-in-one winding often goes past 5KHz. Two-bobbin windings often fall off before 1KHz.