" Eleventeen, wouldn't the tone stack like the Tweed Deluxe go between the plate of the 12AX7 and to the grid of the 6AU6, that is the way it is
set up now for the volume."
It might...and then again, it might not. Yes, that's the generic "positioning" of a tone stack, but without the resources to fiddle with the gain before the stack and the gain after the stack (the TS eats a fair amount of gain) it's not trivial to do so without true mathematical circuit analysis. Or certainly, a much better guesstimate than I can furnish. PRR or HBP or a few others here could do it. Because the topology of this circuit is kind of on the odd side (compared to Fender amp style) I'm reluctant to opine "you can just throw it in there. OTOH, I myself might physically build it (without doing any calcs) and throw it in there and see how it worked and then try to tweak it to my liking. I myself can't give you an algorithm such as "change R42 to 47K and R49 to 33K". With a cigar box full of parts, I might well try to actually *do* something kinda like that with the idea that if I backed myself into a corner I could rip it all out and restore things to stock.
OTOH, I myself would probably lean towards ripping the whole thing apart and building a 5E3 from scratch, including replacing the 6AU6 (a 7-pin tube) with another 12AX7 ( a 9-pin tube, implying a socket change, implying slightish metalwork) but also implying moving directly towards the known-to-work with a parts list that I could know the price of, buy, and shove in there with 90+% confidence that it would all work out at known cost and known time expenditure. I'd probably want to move to a solid state rectifier to crank the B+ up some, say 35-50 volts, as well. This happens because the voltage drop across the 6X4 tube rectifier goes away.
There's every reason to believe that with the 6AU6 pentode after a tone stack, one could recover the losses that the tone stack is expected to produce. There's also good reason to believe that both the first triode of the 12AX7 AND the 6AU6 would want to see higher plate voltages than 75 and 40 volts, respectively. In other words, the tube sections are there, but there would almost certainly be a requirement to fiddle with the pre and post tone stack gains, mostly by changin plate resistors. One would probably want to add/adjust cathode resistors. It doesn't sound like you're equipped to make those changes so I am kinda discouraging you from starting. These things are not difficult to do but it is essentially impossible to do without a pile of resistors and caps of various values you can throw in and see how it works....or not.