Soldered joints should not have large galvanic corrosion. They may on a boat, but do you throw your amps in the sea? Damp sheds are bad, but if an amp is in a damp shed that long the owner has obviously lost interest and deserves corrosion.
For area (diameter squared):
Gold is not as good as copper! Gold doesn't tarnish, so gold plate is good for surface contacts (switches, jacks, parts to be soldered later), but not for carrying electrons over a distance.
Silver is 5% better than copper. Use silver to impress the customer, not the electrons! Next-gauge-up Copper is just as good as Silver. Double-diameter Copper is nearly 4X better and still cheaper than Silver.
For similar Ohms you need this much area:
Copper = 1X (reference)
Silver = 0.95X
Gold = 1.4X
Aluminum = 1.6X
Zinc = 3.7X
Brass, Bronze = 4+X
Iron, Steel = 7X
Because steel is much cheaper than Copper per volume, steel is a very valid conductor where space is not tight. Problem is that steel rusts worse than Copper which makes for poor electrical connection.
The amount of Zinc on Galvanized is so small that it hardly affects the conductivity of steel fence-wire. It does greatly reduce rust and can be soldered with less aggressive flux (maybe rosin instead of acid). Zinc fumes should not be a problem at solder temperature (but welders beware). (Many European languages call Lead-melting and Iron-melting by the same word, "welding". In electronic assembly we only do lower-temperature Lead/Tin melting.) Zinc popping suggests poor Zinc taken too hot.
Brasses and Bronzes have Copper but tend to conduct more like the alloying metal (Zinc, Tin, others).
We do NOT need huge conductivity for tube amps or for SS preamps. Almost any metal, if heavy enough to stand amplifier mechanical abuse, will conduct good enough for our purposes.
The major "loop" problem is around the PT, rectifier, and first filter cap. This loop should be wired as direct as possible. There should be only one connection from this loop to the rest of the amp. Yes, some schemes route rectifier spikes through a short length of chassis. (PT CT to PT bolt, first cap bonded to chassis nearby.) If short, tight, right, this works fine in tube amps. 2 inches of steel 0.050" thick and say 2" wide is a fat conductor. Carrying rectifier spikes long distances over chassis is liable to inject buzz everywhere.