1) V3 plate 6 measures 16v (should be 100v); I cannot figure why; meas 315v on the other side of R34 which meas 94kohm; I also measure 55v at V3 pin2 (is that right). Any thoughts?
the bottom half of that 6CG7 (1,2,3) is a cathodyne phase spliter. The top half (6,7,8) is a gain stage. voltages say something is seriously wrong there. measure the resistors surrounding that triode and -even easier- swap the 6CG7 from the reverb driver. in the end, that triode should have 0VDC on grid, 100VDC on plate and (schematic says) 4VDC on cathode.
2) V6 trem has fluctuating voltage on plate 6, is that expected? I have no tremelo experience, no footswitch either
yes, thats normal. ground the trem jack to get steady VDC readings.
4) How does the PS create DC at the front end of the choke 1? Seems that it just comes directly from secondary. I measure 325vdc at the output side of the choke.
In that arrangement of caps C26-C29 and diodes you have two voltage doubler circuits, one stacked on top of the other.
There is a junction identical to the C26/C27 below it at C28/C29, but they didn't try to "use" that junction to supply voltage to the circuit like they do at C26/C27. The choke passes VDC and blocks VAC, so any VAC at C26/C27 doesn't make to the screen supply & B+ for triodes.
I think there were other threads in this forum in the past with much better explanations by gurus. So I'd search for 1484 up above.
It's amazing that Danolectro found that all those components and the level of effort to assembly them cost less than a more traditional arrangement (that they used in smaller amps).
Also, I always mention this in 1484 threads: the reverb driver 6CG7's two plate resistors 27K are under spec'ed at 1/4W. the voltages on the schematic tell you that. They need to be 1W. On the one I had these two resistors failed open.