When I google Dynaco A-431, several postings suggest a primary impedance of 4.3K ohms, with secondaries for 4, 8, and 16 ohms. 4.3k is definitely in the "normal" range for a pair of 6L6 tubes.
But the next logical questions are, how are the two 8-ohm'ers wired (series=16? or parallel=4?), and what secondary wire might be hooked up to the speakers?
Can you see multiple secondary wires? Any chance you see Black, Brown, Orange and Yellow for secondary wires?
One posting for a pair of Dynaco A-431s says: "Secondary G (Black) to 4 Ohm (Brown) 8 Ohm (Orange) 16 Ohm (Yellow)". I can't vouch for accuracy. It's from the internet after all. And I have no idea how many versions of the A-431 might exist, but if I had to bet I would guess this is pretty standard.
So if you see a Brown wire connected to a 4 ohm load, or a Yellow wire connected to a 16 ohm load, there's a good chance everything is all lined up as it should be. [Edit - Just seeing your gut shots now, but I can't tell for sure: is it Black and Orange going to the speaker jack? And maybe Brown and Yellow are tied off with shrink tube?]
If this "informed guess work" doesn't satisfy, again you could feed the primary some AC, measure AC on the secondaries, and do the calculations I mentioned at the link in my previous post.