Thanks everyone for your help so far!
I need to make up some cables to hook my signal generator in and rig up a dummy load, which I will do soon.
In the meantime, and following some more probing, I found an error in the schematic, which indicates the PI being powered from the C node (325V at ~7mv p-p ripple), but in reality it is taking power from the B node (356V at 140mv p-p ripple). The wiring is pretty neatly done and looks factory to me, so I presume this is the way the amp was built.
In any case, the ripple is entering the signal path in the phase inverter: at pin 2 on the phase inverter (first grid), there is no ripple, whereas on the first plate (pin 1), the ripple is 40mv p-p, and this carries through obviously to the second grid and thus to the second plate.
I tried jumpering in the extra 100uf section in parallel on the B node, which brought the ripple down to about 45mv p-p at the node (making it ~20mv at PI pin 1) and lowered hum significantly. So I have three questions now:
1. Should I try moving the PI B+ to the C tap, as indicated in the schematic?
2. Will the additional 100uf section at the B (or C, if I move the PI to the C node) node cause any problems?
3. Can I add another smaller electrolytic to ground directly at pin 1 to further clean things up, or will that simply short all the signal to ground? If it were feasible, would its effect be negated by the ripple on the phase inverter's second plate, and if so, would there be any advantage to doing the same at the second PI plate? If this does make sense, what size capacitor would be appropriate?