> an EF86 stage for experimenting with the tonal variation.
"Tone" in this context means pushing near OverLoad.
Plot the signal levels through the amp. You have up to 40V at output tube grids, gain near 15 in logtail PI, etc to the front.
See pic below.
I estimate 1V out of the pentode and its CF. It can make maybe 60V; however anything over 1V at pentode plate means heavy 6V6 clipping so pentode "flavor" is quite clean until long past the point the 6V6es are flat-topped. I feel it will not have "tone", it will be a "clean" boost.
I also see very small input sensitivity: 2mV. This is a LOT of gain. Maybe it won't be that extreme. And of course you can turn-down the Volume pot. See the (alternate levels) for turn-down use. However this leads to the signal at pentode grid being lower than at the input: hiss is dominated by the second stage (under our control) rather than by the source (arm and pickup; nominally not under the amp-designer's control).
For pentode flavor, put the pentode where it will work HARD. Unless you play very gently, actually the first stage is hard-worked. Strong strum may be 200mV, pentode gain ~~100, plate level is 20V. This is higher than any other point in the amp until 6V6 grids. The 6V6 driver would be another good place, but push-pull may negate some of that "tone" you know from SE pentodes.
> I don't want super hi gain.., so I was thinking of a lowish screen voltage
Low G2 voltage gives high gain. For low gain, nail G2 to +300V, increase Rk to get plate voltage in a zone.
> what the benefit of the AC cathode follower
Pentode gives higher gain "because" it has very high plate impedance. If you use a 470K plate resistor to drive a 220K tone-stack, gain falls badly.
BTW, distortion ("tone") is reduced by buffering.
However here we have 100K plate resistor and 750K load. Loaded gain is 88% of un-loaded gain, a 1dB difference, not audible. If it were mis-biased to distort... but it is "well"-biased, and it runs at 1/60th of overload, it's clean as a cat's nose.