16-input passive mix networks are very common.
> into a Cathode Follower
No, you don't need high impedance. But you do need GAIN (with low noise). With 16 inputs the output is 1/15th of one input. You first need to boost-up weak signal by 1:15; or mix strong signals and have gain of 15 after the mix network to get back to a strong signal.
> Mr. Merlin say that probably 4 is the max number
When you have weak (pickup) signals and NO pre-mix boosting, as shown in his input-jack mixers.
You can build 2, 4, 16 preamps (tube-stage or two with gain control) and then mix them all together just fine.
Richard's "Altec mixer" with 5 inputs is a good model. Five 330K (near-enough Fender's 270K or 220K) with preamps on weak sources (just a pot on In5 which comes from Musak with strong level) into a simple gain stage.
Somewhere north of 8 or 16 the losses get large, or signal dips toward noise; also a 64-input console is physically very-very wide. Huge mixing jobs are sometimes broken into stages: eight 8-into-1 mixers, boosters, a final 8-into-1 mixer, booster.
Don't be too attracted to Merlin's "feedback mixer". It does reduce interaction between controls. Some mix enginers do not want the singer to fade when you boost the cow-bell. A badly proportioned passive mixer sure will do that. A well-proportioned passive mixer may dip slightly and perhaps "naturally" (less singer leaves more room for cowbell). The interaction should be less with more channels. A good feedback mixer, you can run 0VU in channel 1, then slide ch 2-64 to ANY position, and the ch 1 signal stays 0VU spot-on.