I agree that you want the actual Uberschall schematic, as our guesses from a different amp's schematic may not be right.
But...
The Triple Giant schematic shows series and shunt optoisolators for every channel except the clean channel; that one uses only a series opto. The scheme seems to be when you want "not clean" the LED is turned off and the opto becomes a big resistance. At the same time, one of the distortion channels has its pair of optos switched to the opposite state. I mean, the shunt opto is turned off (no longer shunting signal to ground) and the series opto is turned on (becomes a low resistance and lets the signal through).
My guess is that the opto you measured the strange voltage on is a bum opto. Or, the relay driving that opto isn't giving a low resistance path for current. But I strongly suspect the opto, because generally LEDs clamp an applied voltage to a specific level, and you merely adjust the current through them through an external resistor. That resistor could be made bigger to lower the LED current and brightness. I'm guessing the LED in the suspect opto is bad, and isn't turning on bright enough to reduce that opto's resistance very low. That might account for the weak, distorted sound of the clean channel.
But you'll want to review the schematic, and cross-check the on-voltage of the opto in question. Of course, there's a chance the driving relay is faulty, etc.