Inset the follower after the Mix pot, correct?
Add the new gain stage, then the new cathode follower after the Mix pot. Remember, you're trying to hit line level after all that stuff.
I'd need yet another pot after that for "level"?
Maybe, but we're spending time trying to boost the signal to get your line level, so throwing it away seems like a step back. I'd think you'd want to adjust the signal level before the reverb's input to adjust overall signal level. My concern is that adding another pot may just be adding a new place to misadjust and get more noise. Of course, you could always try adding a level pot then removing it if it doesn't work properly.
Maybe a level pot immediately after the Mix pot and before the new gain stage. Breadboarding this is probably the best way to figure out what will work best, before building a nicely-crafted finished project and then ripping out/moving various bits.
Also going to want to stick a TMB in there somehow.
Are you sure? Have you tried this kind of circuit with the existing tweed-type tone control?
I ask because this is the standard Fender 6G15 Reverb, and the stock tone control does a pretty good job shifting the reverb tone.
Adding the TMB circuit will entail more signal loss, meaning more to make up somewhere, with more opportunity to add noise, etc. Second, this circuit isn't a stand-alone guitar preamp, and still needs a guitar amp's preamp to boost/shape the signal.
And if you're thinking about tonal control for your recordings, isn't that better accomplished through more elaborate EQ's in your DAW?
I'm still confused, do you want to build;
1. Stand alone reverb for guitar?
2. Build it for line level signals to use with the DAW/loop?
3. Build it to use for both?
I think #3 would be best but maybe too complex for me at this point.
No it's not.

You know the output of the Mix pot is good for guitar-signal output into an amp, as this was designed to do.
Notice the Output jack is drawn as a switched jack, shorting the hot to ground. This is probably silly, because if you unplug from the output jack, you won't hear any noise anyway. So let's re-purpose that switched contact.
Disconnect the switched contact lug from the ground lug. Add a wire from the switched contact lug to the grid circuit of your new gain stage (with the cathode follower after the gain stage, and a line-level output jack).
Now, the jack after the Mix pot is your "guitar-level output" and is normaled to pass signal to the line-level circuit. If you plug into that output, you break the connection to the line level section automatically.
Things will only get complicated if you want to have both guitar-level output
and line-level output at the same time. Even that shouldn't be a big deal, but I'd have to think more that 20 seconds to come up with a good solution.
