Heard a demo of a Trinity 5E3 on Youtube and has more grind and is much more compressed then the Tube Doctor version. ...
Are you playing the same guitar & the same setting as that guy for
all comparisons? If not, you're comparing apples to T-bones.
That said, there is some recording trickery to his demo. I've got a 5E3 copy I built, and I used to own a '55 Tremolux (basically a 5E3 with tremolo).
The recorded demo sounds more compressed than my amps, and I'm betting the guy used compression to get an even, high volume level for his video. The tip-off is that the clean sounds are basically as-loud as the distorted sounds. In person, the distorted sounds may not hit a higher peak voltage on the speaker, but will give the impression of being louder.
He says "no compression" but his recording has a slight bit of reverb to it (you can hear that in the "Long Cool Woman" quote if you use headphones). I bet he at least normalized the volume levels of the different sections, which will give an impression of compression.
Also, if you're not playing as brightly as he is, or if you used a different speaker with smoother highs, your amp will sound "less crunchy". If you want more rasp, turn up the treble. He may not have EQ'd the track, but he uses a Shure SM57 (which has an EQ curve with a presence rise) and an AKC condenser mic (which will also likely bump up highs a bit); these will probably make the recording "brighter than live".
Not a knock against that guy or his claims, just that microphones impart their own sonic signature.
Main voltage differences between the two -
V1 pin 1 - Trinity 131.2v TAD 116.5v
V1 pin 6 - Trinity 135.7v TAD 121v
V5 pins 4 and 6 - Trinity 366v TAD 326v
This is almost "no voltage difference". V1 Pin 1 is 11.2% lower, V1 Pin 6 is 10.8% lower and V5 is 10.9% lower.
What could account for this? The voltage at the rectifier of your amp is lower than the Trinity amp by essentially the same fixed percentage as every other part of the amp. So that's why the difference: either your output tubes are pulling a little more current and dropping the B+ a bit (which seems likely as you noted you had a couple more volts at the 6V6 cathodes), or your power transformer is outputting a tad less voltage.
Overall, that's probably a good thing, as you're likely to run into a situation where wall voltage is higher than you have at the moment, and B+ will be pushed upward. And most people run into the problem of having too much B+ voltage because their new production 5Y3 has less internal resistance than original 5Y3's.
I think you'll run into distortion a hair quicker with the lower B+ you have now.