In the schematic in the link below for a dual channel JCM800, the PI has some grid values I've never seen and not in balance. Any reason for this that i'm missing? ...
The low value for R41 (330kΩ) is not that out of line with some I've seen. Due to bootstrapping its effective value is higher, meaning it can be made smaller than a typical grid reference resistor and still not load down the previous stage. If its value was small and C25's value was also small, then bass would be somewhat rolled off going into the phase inverter. But C25 is relatively huge at 0.022uF (where 0.001uF or so might be typical).
Not sure about a reason for differing values for R41 and R44. There should be no significant current flow through either resistor, so the voltage at the grids of the phase inverter will be equal and the same value as the voltage at the top of R45.
GUESS: The phase inverter is the first stage inside the feedback loop (from phase inverter to speaker output). The interaction of C30 and R44 causes a low frequency roll-off, and making R44 smaller shifts that roll-off higher. If there were too many roll-offs too close to each other inside the loop, then the negative feedback could become positive at the frequency of those roll-offs. Given this spot in the phase inverter is also the feedback input, I'm thinking they were trimming one of the phase shifts in the feedback loop to ensure stability.