Is there a minimum wattage value for the 100K resistor?
Teach a man to fish... Learn to use Ohm's Law and the Equation for Power.
Ohm's Law: Current = Voltage/Resistance
Power = Voltage * Current
Use algebra to rearrange the Ohm's Law equation to solve for the quantity you don't already know, and substitute Ohm's Law into the Equation for Power to reduce the number of steps.
Power = Voltage * Current
= Voltage * (Voltage/Resistance) (from Ohm's Law)
= Voltage
2/Resistance
If you have a supply voltage of 500vdc and a 100kΩ resistor, then resistor dissipation is no more than Voltage
2/Resistance = 500
2/100k = 2.5w. Double that so the resistor doesn't cook, and you'd get a 5w resistor (which are hard to find in a 100kΩ value).
The resistor wattage rating is entirely dependent on the dc volts you use to form the cap. if you only use 200vdc, the 100kΩ only needs to be 1w (do the math & see what you come up with).
How do I measure the leakage current ...?
Say you have everything connected. Disconnect the 100kΩ from your power source. Connect the red lead of your meter (set to measure current) to the power source, and the black lead to the 100kΩ resistor. Now the meter is in series with the current you're trying to measure. When you first apply power, the current will spike to a high value, but it quickly settles down to a low value (how quickly depends on the resistor).
A perfect cap charges to the full value of the supply voltage you're using, then drops to a measured current of zero. Electrolytic caps aren't perfect, and usually have some residual leakage current. I wouldn't be surprised by 1mA reading on a new cap with the setup I described. I would view any cap passing 10mA after charging as a candidate for the trash can. The better the cap, the less current after it fully charges.
I would use turrets and some G-10 to make a board. I would solder each cap onto the board and unsolder it when it is done. I would attach the board to probably another piece of G-10 with some standoffs. Should make it safe.
Don't solder. Do as Sluckey said and use
insulated gator clips, or the banana jack binding posts I suggested (below). Don't forget that if you use a 300vdc supply, the cap will become a 300vdc piranha waiting to bite you. It would probably be good to have the whole item in a plastic box, use the binding posts, have a set of tip jacks to connect the meter, keep the resistor inside the box, have a switch to allow you to discharge the cap without touching it, and extra jacks to allow you to verify the cap voltage is down to 0v before removing from the binding posts. add a 2-conductor cable from inside the box to insulated gator clips/connector of your choice to connect to your source of d.c. voltage.
I'd draw it out for you, but I'm on a new computer with no way to draw. If the above isn't so clear to you to be ridiculously-obvious, don't build/do it because the cap will be a major shock hazard and you'll only make a silly mistake once (I've been bit by 450vdc, and you don't want to feel that).
