Nicely done!
V4 196/263 0 2.1/2.6 <<----I take it this means that these are two measurements [plate / cathode] taken with volume = "low" and "high", "high" being where you have a problem. I can't see those numbers being right.
I'm stumped as to how the setting on your volume control (which sits in between halves of V1 - first preamp) could affect voltages on V4 . But I smell HF oscillation.
If this was built from a kit, probably you wired the output transformer blue to one plate and brown to the other and those colors were diagrammed out for you and you wired them properly.
But at the risk of sounding silly, it is an absolute requirement that the OT is properly phased. No matter what any diagram says. It *is* possible that a given manufacturer could supply one flavor of OT one month and find a better deal or run out of one type and substitute another type the next month. And oops, still send the same diagram. So, I believe it is a small possibility that your OT is not properly phased---which means you have to flip and test whether (either, not both) the primary or secondary are flopped, phase wise.
Most amps will motorboat or oscillate at *any* volume level with the OP phase reversed. Some don't. So...if you are following what I'm saying, you have to test this on at least an experimental basis. Because NOTHING ELSE will fix it if this is the problem, you sort of have to prove it not to be the problem, at least in my peanut brain. I'd assume you've already cut the blue & brown plate wires to length so those are not easy to flip---though you could, by tacking in some short wires for test purposes. (High voltages there, right?) But you could try flipping the green and black on the output leads. If you flip the wires and you get immediate oscillation or the problem is much worse, then it was right the way it was. False alarm, flip them back. Just make the flip on a temp basis---tack solder the wires. EITHER pri or secondary: Not both. (The preference is to flip the blue & brown)
Yeah, it sounds stupid, but if it's wrong, it will never ever work right misphased.