Don't know if it helps smooth anything out, but I do think some of it is Snake Oil.
I'm a bit skeptical too Ed but that's interesting about the cap info. I've heard that caps get used to working at a certain voltage or range? Seems a bit like forming filter caps to me? But maybe there's something to this? We've all heard of power tubes being burnt-in besides speaker break-in. But on a PRS amp building vid it was more of a testing thing than an amp being left on over night or a few days for the sake of letting it run for some length of time. But I've seen a few vids where a builder will do this (and nothing more is said about it).Heck if the outside foil can make a difference then maybe there is something Sozo & Jupiter knows that we don't?
I was given a huge box of Sozo caps. Yellows, vintage and some of the blues. Long story short, Sozo was making good on a bet they lost and a friend of mine gave them to me. I still have a bunch and use them everywhere. No I say that to say this. I have quite a bit of experience using them and find them to have a nice Mallory type tone, but 100 hours. I just don't see how.
I still grab every blue molded I can get as I like them the best overall, but it is amazing how close the Xicon caps sound to them.
I do think it is a good idea to operate new builds. I was on a run building clones of the 63 Vibroverb for a few guys. If I do make an amp for someone I will take the time to break-in everything for about 3 days. I normally use Black Sabbath.

Serious.
Interesting tidbit. I had 2 of the amps I built over at the house a few weeks ago and these amps are exactly the same. I even made sure the tapped treble pots measured the same. Same speakers, everything. Both guys love the amps and the amps sound different, surprisingly different.
What makes the difference is one has a smooth plate Telefunken in V2 and the other has a NOS RCA white letter blackplate from 1957. All else is the same. This is probably the largest difference I have heard in 2 amps that are the same. I put new Gold Lions in the same place in both amps and they sounded almost the same. That is the first time I really took notice of how much the first tube sounds.
I gusee what I am saying