This is a really old post but I wanted to chime in.
I want to investigate as I find it interesting. I'm an electrical engineer of 40 yrs and electronics hobbyist since age nine when I built my first 6c4 single stage triode amp that ran off a 67.5 volt battery. So, all my life.
I have the instruments to do this. I think it could have to do with much higher stray capacitance thereby cutting the high freq gain. I could also have to do with the taper, combine the factors and they multiply.
The first thing to quantify the observation. Put a signal generator with the target frequency and measure the output for both types. Repeat for several harmonics, maybe 3rd and 5th. That will validate your empirical observation. If it is a frequency related thing. Next an RLC bridge is to characterize the 2 pots. Changes to the circuit can me made to compensate. Although it can be tricky tp boost hi freq gain.
The other thing to do is using the same setup measure both the signal output and the DC resistance for the pot at numbers 1 thru 10 (maybe don't have to go all the way). Plot the result on graph paper with different color pens.
I think the answer will become clear upon those results.
Using the RV4 type pots is a laudable goal as they are just incredibly better and the feel is so nice and smooth. Back when I was still only 19, I worked on a bunch of equipment for an older steel player. I heard him in the music store complaining about his Bigsby volume pedal just not holding up. I approached him outside as said I could fix it. He said I couldn't screw it up any worse than it was, so he gave he shot. I had been tearing apart old military equipment and building audio stuff for years and so I had a lot of those pots in my junk box. I used that along with a nylon gear and flat gear bar that had come out of anther pedal. He told me months later that he absolutely loved it. After that I worked on his twin and fender echo. He even tried to hook me up with he is daughter. But I wasn't ready for anything like that. So that's just a motivational anecdote.
Update: Well, I haven't gotten around to doing all the work above, but I thought up the next best thing: Measure the capacitance from the wiper to the shell with my RLC bridge for both types of pots: The PEC was actually 1 pf lower coming in at 11 pf. That is not enough to make any difference and it actually goes the wrong direction against the theory, however miniscule it is. So, I don't think that has anything to do with it. I'll have to try doing a resistance measurement at different rotation angles to see if it is the taper or starting to wonder if the original poster used a linear unknowingly? I guess after that I'll substitute the 2 types in a build I am doing, but that will be a while. The chassis needs a lot of drilling and cutting and I really hate that work. Been thinking about getting a CNC.
Final Update:
I was recently checking out the difference between some PEC pots I had and discovered one thing that might have started this thread. It may be a simple mistake of using the wrong pot type because the numbering is different. in RV4 pot A and B are both linear 10 and 20 % respectively and C and D are the audio taper pots with 10 and 20 % respectively. That is opposed to Marshall pot types A = audio and B linear. It is possible the original poster used linear pts for both audio and linear.