Hello. I realize this thread is over 120 days old and may qualify as "necro" but since my post here is exactly on topic and only creeps slightly into related topics, I figured I'd better try this first. I'd like to chat about what I think is another factor in how caps can alter sound in guitar amps, or really, any amp, and that factor is ESR, or Efffective or Equivalent Series Resistance.
First in the Power Supply - It is my understanding that ESR not only affects how much ripple is filtered out but also the "flexibility" in regards to the each stage's, and of course especially the power stage's, ease in swinging the power supplied. There is a term, in fact, for this characteristic, which is escaping my memory for the moment, but I imagine anyone who cares about such things already knows exactly to what I am referring - Power Supplies have an effective "impedance". Personally while I, like any vintage amp lover, enjoys a bit of "sag" I prefer to achieve it in other ways than poor filtering. This not only affects tonality and harmonic structure but also that enigmatic dynamic "feel" of guitar amps which are not reproduction devices but musical instruments in their own right.
Secondly, in the Signal Chain - Wherever possible I prefer non-polarized caps in the signal chain, even in bias resistor bypass caps, because polarized are non-symmetrical and this does have an effect on the waveform. I can see it to some degree even on an oscilloscope, to a larger degree on a spectrum analyzer or FFT, and I can hear it. It is somewhat slight especially if only one is swapped out for non-polarized as the effect seems to be somewhat cumulative. That last bit is actually anecdotal since I haven't been able to measure that other than by ear and that can be subjective.
Lastly, and tangential to ESR, is that it seems guitar amps, especially those that are overdriven and there even more especially those that seek to substantially overdrive the power section, sound sweeter if lower values are used early in gain staging coupling caps and get progressively larger as each step to the power section is considered. IOW "trebly" at the front and "bassy" further in.
I'd very much enjoy any comments on these concepts so thank you in advance for any hard data or even imaginative musing.