If your NFB is global - going from the OT to whichever point you decide to insert it - then in my experience, what you'll get is a taming of the overall amplifier - cleaner headroom, less distortion, and a tone you may or may not like. I thought the idea of Marshalls, generally, was balls to the wall (French term for lots of distortion), so it may be that you might prefer "local feedback," where you are basically tweaking a smaller section of the amp (a single amplification stage almost anywhere in the amp) by taking the signal out of that stage and returning it to the input side of the stage, possibly also running it through a filter capacitor or resistor combination. Rob Robinette has posted some interesting local feedback ideas on his site (should show up in a google search), and that's a good starting point. I'm sure builders on this forum have experimented with this endlessly.
What you'll probably have to do, after researching, is pick a couple of ideas that seem likely, then get out the gator clips and try stuff on the workbench until you get the sound you like. It's pretty difficult to determine exactly what sound you'll get from looking at a mod schematic, so you'll probably just have to try them until you get what you want.