My sort of rule of thumb on placing components in the circuit may not be "correct" but it sorta makes sense to me, which is this: if a cap blocks DC, I want it as near the source as possible. That way, there is less DC-loaded wiring in the amp, if you get my drift. So, if there is a 4 inch run from, say, pin 1 of a 12ax7 to the next connection, I'd put the cap as near Pin 1 as possible, because then there will only be an inch of DC loaded wire. (Unless it caused other problems due to lack of space or something.)
This idea seemed a bit silly when it first occurred to me, but when you add up all the wire in the amp, hum and buzz seem to be caused (in my builds at least) by poor lead dressing and layout choices, and using this concept has helped considerably. Hope that's of some help.
Regarding grounding, it looks like you have your pre section going to a ground lug nearby, which I would not do. So, another rule of thumb I've picked up is to float all my grounds off the chassis and then run a star ground from each stage to a single ground lug near the transformer - this means installing terminal strips. Poor grounding schemes have been the single biggest cause of buzz in my builds. With a good star ground, you can experiment if buzz continues, but it usually doesn't.