It looks to me like they mis-identified pins 4 and 6 as pins 3&5? The voltage reference chart is not in agreement with the schematic and I am not aware of any 5U4 tubes using pins 3&5.
Yes, should be pins 4 and 6.
Is the B+ voltage coming off the center tap of the 5V secondary? How does this work?
Yes, the B+ is taken from the 5v CT.
There is no ground reference on the 5v rectifier wind, it floats. That secondary is just a wind of wire, like a choke. But this 5v secondary has a CT. So taking the B+ from the 5v CT, that wind acts like a choke.
Im not sure, but I think on a 5v or 6v heater secondary they wind it with a heavy gauge wire with only a few turns? If so, that would not give much induction, so very low Henri's, mH's? A choke is wound with a thinner gauge wire, more turns, more induction = Henri's, not mH's?
We've had a few guys who had a 5v heater wind with a CT and who tried wiring it both ways, taking the B+ from pin 8 of the rectifier tube and then taking the B+ from the 5v CT. They heard no difference in noise. They were using a GZ34/5AR4 rectifier tube.
But, I've read recently, where they say that you'll only hear a difference with a
directly heated rectifier tube, ie, 5U4, 5Y3.
That said, I'm not sure there's enough induction/Henri's to make any noticeable difference in noise? Although, it can't hurt anything. If I had a PT with a heater CT, I'd use it.
Also, there is no center tap on de 5VAC wiring.
Some PT 5v secondaries do have a CT. Hammond has a number of them. It's an old Hi-Fi thing.