... I'm just trying to get a better understanding of why ... a chassis mounted Zener diode to drop some HT has resulted in a ground loop. ...
Since the 4 parts stop ground loop hum, when you added the chassis-mounted zener you defeated the purpose of those parts & caused hum.
To use your zener
without creating hum requires the "chassis-side" of the zener go to the point marked "GND_MAIN" in your diagram. That is Power Transformer Center-tap ---> Zener ---> GND_MAIN (
not chassis)
Except you can't really do that because of the design of most chassis-mounted zener & the fact they're using the chassis as a heat-sink to achieve their power rating. Which means if you're trying to knock down the supply voltage you probably need to use a different method.
So what about the function of each of the 4 parts?
Problem: The amp's chassis has a Safety Ground that connects to the 3rd wire of the power cord. That connection will go to the outlet, through the 3rd wire of
other equipment, to that other equipment's chassis, and the ground of that other equipment, creating a giant ground loop that picks up hum.
Safety Ground: The chassis connection goes to the building's circuit breaker via a 3rd wire. This is bonded to Neutral (0v) at the service panel, so if a voltage appears on the chassis (which the player could contact & be shocked), then a high current is pulled through the 3rd wire to trip the breaker, removing voltage from the amp. People will break off the ground pin of the power plug, but they're accepting risk for being shocked (and maybe don't realize that).
Resistor: Vox went out of their way to keep the entire amp's Ground System on the circuit board & off the chassis. The Ground System is then connected to the chassis at
only this one point, and the resistor reduces any ground currents that may happen to negligible levels.
Diodes: We want to avoid blowing up the resistor above if a fault situation occurs, so the amp doesn't need to be repaired as a result of incorporating a safety device. If a voltage appears on either the (amp's) Ground System or the chassis that's big enough to burn out the resistor, the diodes take over & pass that current.
Capacitor: The amp chassis is now safe, and the resistor/diodes have separated the amp's Ground System from Safety/Chassis Ground, but we can still encounter odd noises due to radio frequency interference. The Capacitor from Ground System to chassis kills that RF noise without undoing the things we did to kill ground-loop hum.
Check out sections 15.9 and 15.10 of
Valve Wizard's info on Grounding.