I could use some schooling one this subject, specifically what is the difference between shunting highs to ground vs caps on the plate resistor to the power rail. ...
The "Power Rail" is also "AC Ground" if the filter caps are still working well. So technically there should be "no difference" other than it may be physically-easier to install a capacitor-to-"Ground" in one or the other places.
... shunting highs to ground ... caps on the plate resistor ... I have them on my peavey classic 30 ... I have been told they might be to stop oscillation ... i removed them because i felt my amp's top end was mostly in the lower treble ranges and could use some sparkle in the higher registers. ...
The Classic 30 has a Clean channel that is 2 gain stages followed by a Tone Stack, and a Dirty channel that is 4 gain stages (followed by the same Tone Stack).
- The capacitors to "remove highs" (whether going straight to ground or placed across plate load resistors) were likely added to reduce noise & harsh treble with the 4-gain-stage Dirty channel in mind.
- You might tinker C24 (1.5nF to ground) to see how much it impacts treble-reduction, along with C70 (100pF to ground). This is a tricky spot, because R48 (2.2MΩ) is negative feedback that helps set-level for the Reverb side-chain, and the relative-level of the Dry path coming via R29 (150kΩ) and R18 (220kΩ).
- Be aware that "sparkle" may also be hampered/enhanced by the speaker used; many Celestion-type speakers are darker than you might suspect if you do a direct-swap for a Jensen-style speaker. It's pretty hard to overcome speaker-voicing (whether to skew for "better Cleans" or to skew for "smoother Distortion").