The PI is very different than a long tail pair.The schematic is blury at best,even on the mesa tech site.
The two things that are confusing is the phase inverter(different than any I've seen) and the center tap for the low voltage taps goes to the footswitch supply. ???
It's a long-tail, it's just not a typical guitar-amp long-tail.
The 2 triodes are tied together at their cathodes, with the preamp signal going into the "top triode" and the feedback signal going into the "bottom triode". The drawing is quirky, but what also makes it look wierd is that this is essentially a fixed bias version of the long-tail (you could also argue it's cathode biased...).
The real problem is that the cathode resistor is drawn over with the negative supply; it's 15k. It's connected so that its low end is at the negative supply instead of ground, and the high end of the resistor should sit at 2v. The grids of the long-tail are tied to ground through a 150k resistor for the bottom triode and the master volume for the top triode. The feedback circuit is derived and injected a little differently than typical in guitar amps. The real deviation from standard is that there is a 68k resistor on one plate and a 120k resistor on the other plate. A little difference is required to achieve balance in the long-tail, but this might be going a little far on purpose to achieve a sound.
About the footswitch supply: the blue wire on the PT is not a center-tap, just a tap. Even if it was, the red/yellow wire is the one being grounded. So that means there is simply a relatively large a.c. output feeding the negative supplies, with a smaller a.c. output feeding the footswitch supply. The footswitch and EQ supplies have their own rectifiers and filters.