> Old solid state had junctions that did not withstand high voltage, outside of selenium diodes
Selenium rectifier breakdown is low.... under 100V?
But they are basically "plated washers", with a fairly cheap plating (more than zinc, a lot less than pure Silicon). They were stamped out like washers and "stacked" to the desired voltage: a few for 100V, a whole bunch for 1,000V. It is about as exotic as shoving fender-washers in your Chevy until the door and fender are in line.
The most basic Silicon breakdown is 7V. You can tilt this by doping. But if you over-dope, the diode doesn't conduct well. And the required doping must be precise in amount and depth/gradient. It took some years to get this cookie-baking consistent. Which is why you have the 1N4001-1N4008 series. I remember when '01 was cheaper and there was no '08 (it stopped at '07 which was too costly to use casually). Today the '01 and '08 are the same price (in DIY quantity) and there is no reason to use anything less than '08.
In the "2-diode" rectifier plan, the PIV is more than twice your DC voltage. Strictly, it is twice the no-load voltage, plus overhead for line surges. So when using a 50V CT winding to make 70V DC, you need at least 140V PIV and anything less than 200V-300V PIV is risky long-term.
By the same thinking, your "450V DC" amps need 900V diodes, and 2,000V is a better plan. But even well-baked Silicon hardly goes over 1,000V per junction. (Which is already pretty fabulous if you bust-open a diode and look how thin the wafer is, much less the layer which blocks 1,000V.) Moreso since everything today is 5V or 3V and high-volt diodes are going out of fashion. Sluckey had some 10,000V rects and I do not want to know how much his company paid for those.